Heat-resistant nanomaterials can help convert heat into electricity

Micrographs show no noticeable deterioration before and after heat treatment of the material. Credit: Andre Lehnert, University of Michigan

A new nanophotonic material has broken records for high-temperature stability, which could lead to more efficient electricity production and open up a variety of new possibilities in controlling and transforming thermal radiation.

Developed by a team of chemicals and Materials science Engineers, the material controls the flow of infrared radiation and is stable at temperatures of up to 2,000 degrees Fahrenheit in air, an almost double improvement over current methods.

The material uses a phenomenon called destructive interference to reflect infrared energy while allowing shorter wavelengths to pass through. This can reduce heat waste in thermophotovoltaic cells, which convert heat into electricity but cannot use infrared energy, by reflecting infrared waves back into the system. The material could also be useful in photovoltaics, thermal imaging, environmental barrier coatings, sensing, camouflage from infrared monitoring devices and other applications.

“It is similar to the way butterfly wings use wave interference to obtain their color. Butterfly wings are made of colorless materials, but these materials are structured and textured in a way that absorbs some wavelengths of white light but reflects others, resulting in the appearance of color,” Andrej Lenert said, UM Associate Professor of Chemical Engineering and co-author of the study at Nature’s nanotechnology.

“This material does something similar to infrared energy. The hard part is preventing the collapse of that color-producing structure underneath. Hyperthermia. ”

This approach represents a significant departure from the current state of engineered thermal emitters, which typically use foams and ceramics to reduce IR emissions. These materials are stable at high temperatures but provide very limited control over the wavelengths they allow to pass through. Nanophotons could provide more tunable control, but previous efforts were not stable at high temperatures, and often melt or oxidize (the process that forms rust on iron). In addition, many nanophotonic materials maintain their stability only in a vacuum.

The new material solves this problem, surpassing the previous record for heat resistance among stable air Photonic crystals at over 900 degrees Fahrenheit outdoors. Additionally, the material is tunable, allowing researchers to modify it to modulate energy for a variety of potential applications. The research team predicted that applying these materials to existing TPVs would increase efficiency by 10% and believed that much larger efficiency gains would be possible with further improvement.

The team developed the solution by combining expertise in chemical engineering and materials science. Lennert’s chemical engineering team set out to find materials that wouldn’t mix, even if they started to melt.

“The goal is to find materials that maintain nice, clear layers that reflect light the way we want them to, even when things get super hot,” said Lennert. “So we looked for materials with completely different crystal structures, because they tend not to mix.”

They assumed that a mixture of rock salt and perovskite, a mineral made of calcium and titanium oxides, fit the bill. Collaborators at UM and the University of Virginia ran supercomputer simulations to make sure the combination was a good bet.

John Heron, co-author of the study and associate professor of materials science and engineering at the University of Michigan, and Matthew Webb, a doctoral student in materials science and engineering, carefully deposited the materials using pulsed laser deposition to achieve smoothly micro-layered interfaces. To make the material more durable, they used oxides instead of traditional photovoltaic materials; Oxides can be layered more precisely and are less likely to decompose under high temperatures.

“In previous work, conventional materials oxidized under high heat, losing their orderly layered structure,” Heron said. “But when you start with the oxides, this decomposition has already taken place. This results in increased stability in the structure of the final layers.”

After testing confirmed that the material worked as designed, Sean McShere, first author of the study and a doctoral student in materials science and engineering at UM, used computer modeling to identify hundreds of other combinations of materials that would likely work as well. While commercial implementation of the material tested in the study may take years, the fundamental discovery opens a new door of research into a variety of other nanomaterials that could help future researchers develop a range of new materials for a variety of applications.

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more information:
Sean McSherry et al, Nanophotonic control of thermal emissions under air temperature extremes, Nature’s nanotechnology (2022). DOI: 10.1038 / s41565-022-01205-1

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